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Arbeitsgruppe Hecht

Makromolekulare Chemie
Nein

Unsere Arbeitsgruppe konzipiert und synthetisiert (makro)molekulare Bausteine und assembliert/integriert diese in Materialien, die in der Lage sind, mit ihrer Umgebung zu wechselwirken und auf spezifische interne und externe Signale zu reagieren. Synthesebegleitend untersuchen wir die Struktur-Eigenschafts/Funktions-Beziehungen dieser Materialien und aus ihnen hergestellter Bauelemente. Insbesondere, fokussieren wir uns darauf, lichtempfindliche Einheiten zu nutzen, um biologische, chemische und physikalische Prozesse optisch zu kontrollieren und anzutreiben und somit völlig neuartige Materialeigenschaften und Bauelementfunktionen zu realisieren. Primäre Anwendungen liegen auf den Gebieten der Optoelektronik, der Photobiologie/-medizin, dem 3D/4D-Druck und solarbasierten Verarbeitung und Wiederverwertung von Kunststoffen.

Veröffentlichung der Arbeitsgruppe Hecht unter ORCID

Assoziierter Wissenschaftler, Humboldt-Universität Berlin

Prof. Stefan Hecht, Ph.D.

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  • Doktorand*in

    Alwin Drichel, M.Sc.

    T
    +49 241 80-23292
    Raum
    38B213
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  • Doktorand*in

    Anna Jasny, M.Sc.

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    +49 241 80-29943
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    A2.24
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    Anna Jasny
  • Wissenschaftsunterstützender Bereich

    Dipl.-Ing. Bea Becker

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    +49 241 80-23359
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    A 0.20
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    Eleni Sachs, M.Sc.

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    +49 241 80 23372 | 23342
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    Eleni Sachs
  • Doktorand*in

    Kevin Broi, M.Sc.

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    +49 241 80 29945
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    38B 238b
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    Kevin Broi
  • Postdoc

    PhD Bohan Tang

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    +49 241 80-23290
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    38B213
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  • Assoziierter Wissenschaftler, Humboldt-Universität Berlin

    Prof. Stefan Hecht, Ph.D.

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    Portraitbild Prof. Stefan Hecht, PhD
  • Doktorand*in

    Sarah Esser, M.Sc.

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    +49 241 80-29943
    Raum
    38B 217 | 38B 212
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  • Doktorand*in

    Svante Ihrig, M.Sc.

    T
    +49 241 80 23372
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    Büro A 2.13, Labor A 2.24/25
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    Svante Ihrig
  • Doktorand*in

    Tom Bösking, M.Sc.

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    +49 241 80-26153
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    38B217
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    Bösking
  • Projekt

    ULTIMATE

    Bottom-Up Generierung von atomar präzisen synthetischen 2D-Materilaien für hohe Leistung bei Energie- und Elektronikanwendungen
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    Dünne MOF-Filme

    Dünne MOF-Filme mit photoschaltbaren elektronischen Eigenschaften und Ein-Aus-Leitfähigkeit
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    TriggerINK

    Mit Bio-Tinte Knorpel ersetzen
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    MultiGlue

    Multiselektives und -responsives Kleben
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  • Publikation

    Modulating Guest Uptake in Core–Shell MOFs with Visible Light

    D. Mutruc, A. Goulet-Hanssens, S. Fairman, S. Wahl, A. Zimathies, C. Knie and S. Hecht
    Angewandte Chemie International Edition Vol. 58 (37) 12862-12867 (2019)
    https://www.doi.org/10.1002/anie.201906606
  • Publikation

    Modulating the Charge Transport in 2D Semiconductors via Energy-Level Phototuning

    H. Qiu, Y. Zhao, Z. Liu, M. Herder, S. Hecht and P. Samorì
    Advanced Materials Vol. 31 (39) 1903402 (2019)
    https://www.doi.org/10.1002/adma.201903402
  • Publikation

    Imine-based dynamic polymer networks as photoprogrammable amine sensing devices

    M. Kathan, C. Jurissek, P. Kovaříček and S. Hecht
    Journal of Polymer Science Part A: Polymer Chemistry Vol. 0 (0) (2019)
    https://www.doi.org/10.1002/pola.29518
  • Publikation

    Shining a Light on Proteolysis Targeting Chimeras

    E. Teichmann and S. Hecht
    ACS Central Science Vol. 5 1645-1647 (2019)
    https://doi.org/10.1021/acscentsci.9b00955
  • Publikation

    Predicting the yield of ion pair formation in molecular electrical doping: redox-potentials versus ionization energy/electron affinity

    B. Wegner, L. Grubert, C. Dennis, A. Opitz, A. Rottger, Y. D. Zhang, S. Barlow, S. R. Marder, S. Hecht, K. Mullen and N. Koch
    Journal of Materials Chemistry C Vol. 7 (44) 13839-13848 (2019)
    https://www.doi.org/10.1039/c9tc04500g
  • Publikation

    Covalent on-surface polymerization

    L. Grill, S. Hecht
    Nature Chemistry Vol. 12 (2) 115-130 (2020)
    https://doi.org/10.1038/s41557-019-0392-9
  • Publikation

    Simultaneous Optical Tuning of Hole and Electron Transport in Ambipolar WSe2 Interfaced with a Bicomponent Photochromic Layer: From High-Mobility Transistors to Flexible Multilevel Memories

    H. Qiu, Z. Liu, Y. Yao, M. Herder, S. Hecht and P. Samorì
    Advanced Materials Vol. 32 (11) 1907903 (2020)
    https://doi.org/10.1002/adma.201907903
  • Publikation

    Enlightening Materials with Photoswitches

    A. Goulet-Hanssens, F. Eisenreich and S. Hecht
    Advanced Materials Vol. 32 (20) 1905966 (2020)
    https://doi.org/10.1002/adma.201905966
  • Publikation

    Modulating the luminance of organic light-emitting diodes via optical stimulation of a photochromic molecular monolayer at transparent oxide electrode

    G. Ligorio, G. F. Cotella, A. Bonasera, N. Z. Morales, G. Carnicella, B. Kobin, Q. Wang, N. Koch, S. Hecht, E. J. W. List-Kratochvil, F. Cacialli
    Nanoscale Vol. 12 (9) 5444-5451 (2020)
    https://doi.org/10.1039/D0NR00724B
  • Publikation

    From Responsive Molecules to Interactive Materials

    A. Priimagi and S. Hecht
    Advanced Materials Vol. 32 (20) 2000215 (2020)
    https://doi.org/10.1002/adma.202000215
  • Publikation

    Oligothiophene-Based Phosphonates for Surface Modification of Ultraflat Transparent Conductive Oxides

    M. Timpel, M. Nardi, B. Wegner, G. Ligorio, L. Pasquali, J. Hildebrandt, M. Pätzel, S. Hecht, H. Ohta and N. Koch
    Advanced Materials Interfaces Vol. 7 (12) 1902114 (2020)
    https://doi.org/10.1002/admi.201902114
  • Publikation

    Photomodulation of Charge Transport in All-Semiconducting 2D–1D van der Waals Heterostructures with Suppressed Persistent Photoconductivity Effect

    Z. Liu, H. Qiu, C. Wang, Z. Chen, B. Zyska, A. Narita, A. Ciesielski, S. Hecht, L. Chi, K. Müller and P. Samorì
    Advanced Materials Vol. 32 (16) 2001268 (2020)
    https://doi.org/10.1002/adma.202001268
  • Publikation

    Mechanistic Insights into the Triplet Sensitized Photochromism of Diarylethenes

    S. Fredrich, T. Morack, M. Sliwa and S. Hecht
    Chemistry – A European Journal Vol. 26 (34) 7672-7677 (2020)
    https://doi.org/10.1002/chem.202000877
  • Publikation

    Engineering Optically Switchable Transistors with Improved Performance by Controlling Interactions of Diarylethenes in Polymer Matrices

    L. Hou, T. Leydecker, X. Zhang, W. Rekab, M. Herder, C. Cendra, S. Hecht, I. McCulloch, A. Salleo, E. Orgiu and P. Samorì
    Journal of the American Chemical Society Vol. 142 (25) 11050-11059 (2020)
    https://doi.org/10.1021/jacs.0c02961
  • Publikation

    Engineering crack tortuosity in printed polymer–polymer composites through ordered pores

    L. F. Gockowski, N. D. Dolinski, R. Chavez, N. Cohen, F. Eisenreich, S. Hecht, R. M. McMeeking, C. J. Hawker and M. T. Valentine
    Materials Horizons Vol. 7 (7) 1854-1860 (2020)
    https://doi.org/10.1039/D0MH00331J
  • Publikation

    Donor-Acceptor Dihydropyrenes Switchable with Near-Infrared Light

    K. Klaue, W. Han, P. Liesfeld, F. Berger, Y. Garmshausen and S. Hecht
    Journal of the American Chemical Society Vol. 142 (27) 11857-11864 (2020)
    https://doi.org/10.1021/jacs.0c04219
  • Publikation

    Proton‐Gated Ring‐Closure of a Negative Photochromic Azulene‐Based Diarylethene

    I. C.-Y. Hou, F. Berger, A. Narita, K. Müllen and S. Hecht
    Angewandte Chemie International Edition Vol. 59 (42) 18532-18536 (2020)
    https://doi.org/10.1002/anie.202007989
  • Publikation

    Highly Cooperative Photoswitching in Dihydropyrene Dimers

    P. Liesfeld, Y. Garmshausen, S. Budzak, J. Becker, A. Dallmann, D. Jacquemin and S. Hecht
    Angewandte Chemie-International Edition Vol. 59 (43) 19352-19358 (2020)
    https://doi.org/10.1002/anie.202008523
  • Publikation

    Multiresponsive Nonvolatile Memories Based on Optically Switchable Ferroelectric Organic Field-Effect Transistors

    M. Carroli, A. G. Dixon, M. Herder, E. Pavlica, S. Hecht, G. Bratina, E. Orgiu and P. Samorì
    Advanced Materials Vol. 33 (13) 2007965 (2021)
    https://doi.org/10.1002/adma.202007965
  • Publikation

    Xolography for linear volumetric 3D printing

    M. Regehly, Y. Garmshausen, M. Reuter, N. F. König, E. Israel, D. P. Kelly, C.-Y. Chou, K. Koch, B. Asfari and S. Hecht
    Nature Vol. 588 (7839) 620-624 (2020)
    https://doi.org/10.1038/s41586-020-3029-7
  • Publikation

    Photocontrollable Modulation of Frontier Molecular Orbital Energy Levels of Cyclopentenone-Based Diarylethenes

    A. G. Lvov, M. Herder, L. Grubert, S. Hecht and V. Z. Shirinian
    Journal of Physical Chemistry A Vol. 125 (17) 3681-3688 (2021)
    https://doi.org/10.1021/acs.jpca.1c01836
  • Publikation

    Chirality Remote Control in Nanoporous Materials by Circularly Polarized Light

    A. B. Kanj, J. Bürck, N. Vankova, C. Li, D. Mutruc, A. Chandresh, S. Hecht, T. Heine and L. Heinke
    Journal of the American Chemical Society Vol. 143 (18) 7059–7068 (2021)
    https://doi.org/10.1021/jacs.1c01693
  • Publikation

    Ternary-Responsive Field-Effect Transistors and Multilevel Memories Based on Asymmetrically Functionalized Janus Few-Layer WSe2.

    H. Qiu, M. Herder, S. Hecht and P. Samorì
    Advanced Functional Materials Vol. 31 (36) 2102721 (2021)
    https://doi.org/10.1002/adfm.202102721
  • Publikation

    Graphene transistors for real-time monitoring molecular self-assembly dynamics

    M. Gobbi, A. Galanti, M.-A. Stoeckel, B. Zyska, S. Bonacchi, S. Hecht and P. Samorì
    Nature Communications Vol. 11 (1) 4731 (2020)
    https://doi.org/10.1038/s41467-020-18604-4
  • Publikation

    Using Active Surface Plasmons in a Multibit Optical Storage Device to Emulate Long-Term Synaptic Plasticity

    S.-Y. Rhim, G. Ligorio, F. Hermerschmidt, J. Hildebrandt, M. Pätzel, S. Hecht and E. J. W. List-Kratochvil
    physica status solidi (a) Vol. 217 (20) 2000354 (2020)
    https://doi.org/10.1002/pssa.202000354
  • Publikation

    Tunable Photomechanics in Diarylethene-Driven Liquid Crystal Network Actuators

    M. Lahikainen, K. Kuntze, H. Zeng, S. Helantera, S. Hecht and A. Priimagi
    ACS Applied Materials & Interfaces Vol. 12 (42) 47939-47947 (2020)
    https://doi.org/10.1021/acsami.0c12735
  • Publikation

    Control of long-distance motion of single molecules on a surface

    D. Civita, M. Kolmer, G. J. Simpson, A.-P. Li, S. Hecht and L. Grill
    Science Vol. 370 (6519) 957-960 (2020)
    https://doi.org/10.1126/science.abd0696
  • Publikation

    Light-mediated chiroptical switching of an achiral foldamer host in presence of a carbohydrate guest

    S. Pramanik, B. Kauffmann, S. Hecht, Y. Ferrand and I. Huc
    Chemical Communications Vol. 57 (1) 93-96 (2020)
    https://doi.org/10.1039/D0CC06484J
  • Publikation

    Tough Multimaterial Interfaces through Wavelength-Selective 3D Printing

    N. D. Dolinski, E. B. Callaway, C. S. Sample, L. F. Gockowski, R. Chavez, Z. A. Page, F. Eisenreich, S. Hecht, M. T. Valentine, F. W. Zok and C. J. Hawker
    ACS Applied Materials & Interfaces Vol. 13 (18) 22065-22072 (2021)
    This is an external publication.
    https://doi.org/10.1021/acsami.1c06062
  • Publikation

    Accelerated Discovery of α-Cyanodiarylethene Photoswitches

    N. F. König, D. Mutruc and S. Hecht
    Journal of the American Chemical Society Vol. 143 (24) 9162-9168 (2021)
    https://doi.org/10.1021/jacs.1c03631
  • Publikation

    Avoiding the Center-Symmetry Trap: Programmed Assembly of Dipolar Precursors into Porous, Crystalline Molecular Thin Films

    A. Nefedov, R. Haldar, Z. Xu, H. Kühner, D. Hofmann, D. Goll, B. Sapotta, S. Hecht, M. Krstić, C. Rockstuhl, W. Wenzel, S. Bräse, P. Tegeder, E. Zojer and C. Wöll
    Advanced Materials 2103287 (2021)
    https://doi.org/10.1002/adma.202103287
  • Publikation

    Stabilizing Indigo Z-Isomer through Intramolecular Associations of Redox-Active Appendages

    L. Broløs, K. Klaue, J. Bendix, L. Grubert, S. Hecht and M. B. Nielsen
    European Journal of Organic Chemistry Vol. 2021 (46) 6304-6311 (2021)
    https://doi.org/10.1002/ejoc.202100781
  • Publikation

    Reversible Training of Waveguide-Based and/or Gates for Optically Driven Artificial Neural Networks Using Photochromic Molecules

    S. Y. Rhim, G. Ligorio, F. Hermerschmidt, M. Patzel, M. Herder, S. Hecht and E. J. W. List-Kratochvil
    Journal of Physics D-Applied Physics Vol. 55 (4) 44002 (2021)
    https://doi.org/10.1088/1361-6463/ac2d62
  • Publikation

    A Photoprogrammable Electronic Nose with Switchable Selectivity for Vocs Using Mof Films

    P. Qin, S. Okur, C. Li, A. Chandresh, D. Mutruc, S. Hecht and L. Heinke
    Chemical Science Vol. 12 (47) 15700-15709 (2021)
    https://doi.org/10.1039/D1SC05249G
  • Publikation

    Diarylethenes in Optically Switchable Organic Light-Emitting Diodes: Direct Investigation of the Reversible Charge Carrier Trapping Process

    G. F. Cotella, A. Bonasera, G. Carnicella, A. Minotto, S. Hecht and F. Cacialli
    Advanced Optical Materials 2101116 (2021)
    https://doi.org/10.1002/adom.202101116
  • Publikation

    Binding of a Tlcl Entity by a Tetragold Tetramercaptothiacalixarene Metalloligand Via Metallophilic Interactions

    N. Frank, I. Pryjomska-Ray, L. Grubert, S. Hecht, D. Usvyat and C. Limberg
    Chemistry – A European Journal Vol. 27 (32) 8344-8349 (2021)
    This is an external publication.
    https://doi.org/10.1002/chem.202100298
  • Publikation

    Mechanistic Insights into the Photoisomerization of N,N′-Disubstituted Indigos

    Š. Budzák, J. Jovaišaitė, C.-Y. Huang, P. Baronas, K. Tulaitė, S. Juršėnas, D. Jacquemin and S. Hecht
    Chemistry – A European Journal e202200496 (2022)
    https://doi.org/10.1002/chem.202200496
  • Publikation

    Solving the Azobenzene Entropy Puzzle: Direct Evidence for Multi-State Reactivity

    M. Reimann, E. Teichmann, S. Hecht and M. Kaupp
    The Journal of Physical Chemistry Letters Vol. 13 (46) 10882-10888 (2022)
    https://doi.org/10.1021/acs.jpclett.2c02838
  • Publikation

    A General Approach for All-Visible-Light Switching of Diarylethenes through Triplet Sensitization Using Semiconducting Nanocrystals

    L. Hou, W. Larsson, S. Hecht, J. Andréasson and B. Albinsson
    Journal of Materials Chemistry C Vol. 10 (42) 15833-15842 (2022)
    https://doi.org/10.1039/D2TC03582K
  • Publikation

    Combination of Knoevenagel Polycondensation and Water-Assisted Dynamic Michael-Addition-Elimination for the Synthesis of Vinylene-Linked 2D Covalent Organic Frameworks

    Dr. Shunqi Xu, Dr. Zhongquan Liao, Dr. Arezoo Dianat, Dr. Sang-Wook Park, Dr. Matthew A. Addicoat, Dr. Yubin Fu, Dominik L. Pastoetter, Filippo Giovanni Fabozzi, Dr. Yannan Liu, Prof. Gianaurelio Cuniberti, Dr. Marcus Richter, Prof. Stefan Hecht, Prof. Xinliang Feng
    Angewandte Chemie - International Edition Vol. 16 (21) e202202492 (2022)
    https://doi.org/10.1002/anie.202202492
  • Publikation

    Continuous Volumetric 3D Printing: Xolography in Flow

    L. Stüwe, M. Geiger, F. Röllgen, T. Heinze, M. Reuter, M. Wessling, S. Hecht and J. Linkhorst
    Advanced Materials Vol. 36 (4) 2306716 (2023)
    https://doi.org/10.1002/adma.202306716
  • Publikation

    Revisiting Peri-Aryloxyquinones: From a Forgotten Photochromic System to a Promising Tool for Emerging Applications

    A. G. Lvov, L. S. Klimenko, V. N. Bykov and S. Hecht
    Chemistry – A European Journal e202303654 (2023)
    https://doi.org/10.1002/chem.202303654
  • Publikation

    Photoswitchable Quadruple Hydrogen-Bonding Motif

    B. Tang, M. Pauls, C. Bannwarth and S. Hecht
    Journal of the American Chemical Society (2023)
    https://doi.org/10.1021/jacs.3c10401
  • Publikation

    Room Temperature on-Surface Synthesis of a Vinylene-Linked Single Layer Covalent Organic Framework

    F. G. Fabozzi, N. Severin, J. P. Rabe and S. Hecht
    Journal of the American Chemical Society Vol. 145 (33) 18205-18209 (2023)
    https://doi.org/10.1021/jacs.3c04730
  • Publikation

    Photoswitchable Inhibitors to Optically Control Specific Kinase Activity

    T. Aguirre, E. Teichmann, F. Q. Römpp, R. Vivier, C. Bryant, M. A. Hulverson, W. C. Van Voorhis, K. K. Ojo, J. S. Doggett, D. Fiedler and S. Hecht
    ACS Chemical Biology Vol. 18 (6) 1378-1387 (2023)
    https://doi.org/10.1021/acschembio.3c00119
  • Publikation

    Optical and Chemical Control of the Wettability of Nanoporous Photoswitchable Films

    Z. Zhang, D. Chen, D. Mutruc, S. Hecht and L. Heinke
    Chemical Communications Vol. 58 (100) 13963-13966 (2022)
    https://doi.org/10.1039/D2CC03862E
  • Publikation

    Red-Light Photoswitching of Indigos in Polymer Thin Films

    K. Kuntze, J. Viljakka, M. Virkki, C.-Y. Huang, S. Hecht and A. Priimagi
    Chemical Science Vol. 14 (10) 2482-2488 (2023)
    https://doi.org/10.1039/D2SC06790K
  • Publikation

    Diaryltriazolium Photoswitch: Reaching a Millisecond Cycloreversion with High Stability and NIR Absorption

    D. Kolarski, P, Steinbach, C. Bannwarth, K. Klaue and S. Hecht
    Angewandte Chemie International Edition Vol. 63 (8) e202318015 (2023)
    https://doi.org/10.1002/anie.202318015
  • Publikation

    Functionalization of a Zirconia Surface by Covalently Immobilized Fibronectin and Its Effects on Resistance to Thermal, Acid, and Mechanical Exposure

    A. L. Palkowitz, T. Tuna, R. Kaufmann, E. M. Buhl, S. Wolfart and H. Fischer
    Journal of Biomedical Materials Research Part B: Applied Biomaterials Vol. 112 (2) e35390 (2024)
    https://doi.org/10.1002/jbm.b.35390
  • Publikation

    Azobenzene Isomerization on a Reactive Copper Surface by Efficient Decoupling with Bulky Side Groups

    S. Jaekel, R. Stoll, F. Berger, S. Hecht and L. Grill
    Surface Science Vol. 744 122468 (2024)
    https://doi.org/10.1016/j.susc.2024.122468
  • Publikation

    Li Promoting Long Afterglow Organic Light-Emitting Transistor for Memory Optocoupler Module

    Y. Chen, H. Wang, H. Chen, W. Zhang, M. Pätzel, B. Han, K. Wang, S. Xu, V. Montes-García, I. McCulloch, S. Hecht and P. Samorì
    Advanced Materials 2402515 (2024)
    https://doi.org/10.1002/adma.202402515
  • Publikation

    Solar Azo-Switches for Effective E→Z Photoisomerization by Sunlight

    Z.-Y. Zhang, D. Dong, T. Bösking, T. Dang, C. Liu, W. Sun, M. Xie, S. Hecht and T. Li
    Angewandte Chemie International Edition Vol. 63 (31) e202404528 (2024)
    https://doi.org/10.1002/anie.202404528
  • Publikation

    Accessing a Diverse Set of Functional Red-Light Photoswitches by Selective Copper-Catalyzed Indigo N-Arylation

    A. K. Jaiswal, P. Saha, J. Jiang, K. Suzuki, A. Jasny, B. M. Schmidt, S. Maeda, S. Hecht and C.-Y. D. Huang
    Journal of the American Chemical Society Vol. 146 (31) 21367-21376 (2024)
    https://doi.org/10.1021/jacs.4c03543
  • Publikation

    Voltage-Gated Switching of Moiré Patterns in Epitaxial Molecular Crystals

    F. G. Fabozzi, J. D. Cojal González, N. Severin, J. P. Rabe and S. Hecht
    ACS Nano Vol. 18 (49) 33664-33670 (2024)
    https://doi.org/10.1021/acsnano.4c12708
  • Publikation

    Dynamic Covalent Spiropyran Exchange for Rapid Structural Diversification

    A. Drichel, Y. Garmshausen and S. Hecht
    Angewandte Chemie International Edition Vol. 64 (7) e202419531 (2025)
    https://doi.org/10.1002/anie.202419531

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